Inthispaper,polyvinylidenefluoride(PSF)asthemembranematerial,todimethylacetamide(DMAc)assolventandlithiumchloride(Licl)asadditives,methanol,ethanolandglycerinbathgel,respectively,byimmersionprecipitation-preparedbyphaseinversionwithdifferentmembranecompositionofcoagulationbath.EvaluationofmicrofiltrationmembranedevicewithameasuredwaterfluxandBSArejectionrate.Simultaneousmeasurementofmembranelengthandwidthandtheporosityofwetanddryweightwerecalculated.Investigatedthenatureofcoagulationbathonmembranestructureandmembraneproperties,byregulatingthecompositionofcoagulationbath,accesstothePVDFmembranewithaperformancethan,andtheformationmechanismofphasetransformationwereanalyzed.